Syntheses and characterizations of homoleptic and heteroleptic copper complexes with monocyclic and polycyclic azine ligands

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dc.contributor.advisorOmary, Manal
dc.contributor.committeeMemberMirsaleh-Kohan, Nasrin
dc.contributor.committeeMemberSalazar, Gustavo
dc.creatorKouadio, Halima
dc.date.accessioned2024-02-08T21:23:31Z
dc.date.created2023-12
dc.date.issuedDec-23
dc.date.submittedDec-23
dc.date.updated2024-02-08T21:23:31Z
dc.description.abstractThis thesis is concerned with the following ligands to use to coordinate and react to copper: a pyrimidine: niacinamide, the polyazine monocyclic triazine: cyanuric acid, and bicyclic N- donating hydrocarbons: quinoxaline and caffeine. When reacted with cuprous salts consisting of organic ligands they form multi-ligand coordination supramolecular architectures (1) or halides to form copper halide clusters. In the novel compounds, metal-metal interactions occur, which exhibit low-lying triplet state charge transfers, allowing the tunability of a photon-emitting compound which is expected to form the emission. Cuprous metal centers also possess the ability to self-assemble to form coordination polymers. Group 11 d10 coinage metals exhibit strong metal-to-ligand charge transfers (MLCT) as well.(50) Characterization of all compounds was completed using thermogravimetric analysis, X-ray crystallography, Fourier transform infrared spectroscopy (FTIR), and photoluminescence spectroscopy. The acquired data is analyzed and discussed further in the following thesis.
dc.format.mimetypeapplication/pdf
dc.identifier.urihttps://hdl.handle.net/11274/15744
dc.language.isoEnglish
dc.subjectChemistry, Inorganic
dc.subject.otherInorganic Chemisty
dc.titleSyntheses and characterizations of homoleptic and heteroleptic copper complexes with monocyclic and polycyclic azine ligands
dc.typeThesis
dc.type.materialtext
local.embargo.lift12
local.embargo.terms12/1/2026
thesis.degree.collegeCollege of Arts and Sciences
thesis.degree.departmentSchool of the Sciences
thesis.degree.disciplineChemistry
thesis.degree.grantorTexas Woman's University
thesis.degree.nameMaster of Science
thesis.degree.programACS 3rd edition

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