Synthesis and spectroscopic properties of group 11 coordination polymers with mixed pyrazolate/diimine ligands

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dc.contributor.authorAljomeh, Ghadah A.en_US
dc.contributor.committeeChairRawashdeh-Omary, Manal
dc.contributor.committeeMemberBritt, Mark
dc.contributor.committeeMemberMirsaleh-Kohan, Nasrin
dc.date.accessioned2015-10-12T17:00:22Z
dc.date.available2015-10-12T17:00:22Z
dc.date.copyright2015en_US
dc.date.issued8/30/2015en_US
dc.description.abstractThis thesis is a study of coinage metal complexes with various bridging diimine ligands. It has 91 pp, 8 tables, 65 figures, and references for the study of group 11 elements. It discusses one main project and is divided into three chapters describing in general the synthesis, structure, and spectroscopic studies of silver (I) and copper (I) complexes. Chapter I presents an introduction to the chemistry of trinuclear azolate complexes of group 11 metals, trinuclear azolate complexes of group 11 metals, linearly-bridging diimines, mixed metal and mixed ligands for group 11 complexes, and their potential applications, including metal-organic frameworks (MOFs), solar cells, and organic light emitting diodes (OLEDs). Chapter II describes the synthesis of d10 coinage metal complexes with different organic building ligands. Chapter III discusses the structural characterization and spectroscopy, including x-ray crystallography, photoluminescence, 1HNMR, FT-IR, absorption spectroscopy, and thermogravimetric analysis, of silver complexes, copper complexes, mixed-metal complexes, and mixed-ligand complexes. It also summarizes the conclusion of the results obtained in Chapter II and the expected applications.en_US
dc.identifier.urihttp://hdl.handle.net/11274/7020
dc.language.isoen_USen_US
dc.subjectInorganic chemistry
dc.subjectPure sciences
dc.subjectAzolate
dc.subjectLigands
dc.subjectSolar
dc.subjectSpectroscopy
dc.subjectChemistryen_US
dc.titleSynthesis and spectroscopic properties of group 11 coordination polymers with mixed pyrazolate/diimine ligandsen_US
dc.typeThesisen_US
thesis.degree.collegeCollege of Arts and Sciences
thesis.degree.departmentChemistry and Biochemistry
thesis.degree.disciplineChemistry
thesis.degree.grantorTexas Woman's University
thesis.degree.levelMaster
thesis.degree.nameMaster of Science

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