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Reaction of (Z)- and (E)-β-chlorocinnamohydroximoyl chlorides with methoxide ion
New α,β-unsaturated hydroximoyl chlorides and hydroximates were synthesized and characterized. 13C NMR, 1H NMR, IR and elemental analysis were determined for each new compound. The kinetics of methoxide ion substitution ...
The element effect in methoxide ion substitution of the (Z) and (E) isomers of O-methyl-4-methoxybenzohydroximoyl halides
The (Z) and (E) isomers ofO-methyl-4-methoxybenzohydroximoyl chloride [p-OCH3ArC( Cl )=NOCH3] and 0-methyl-4-methoxybenzohyd roximoyl bromide [p-OCH3ArC(Br)=NOCH3] were synthesized, and the rates of methoxide substitution ...
Mechanisms of acid catalyzed Z/E isomerization of hydroximates
The acid-catalyzed isomerization of methyl O-methylcinnamohydroximate (1Zb and 1Eb) was investigated with four different acids in acetonitrile at 25 °C. There are two reasonable mechanisms in which isomerization can take ...
Synthesis and characterization of group 11 metal multinuclear pyrazolate complexes with ferrocene and its various derivatives
This thesis is a study of coinage metal complexes with various bridging diimine ligands. It has 75pp, 4 tables, 55 figures and the references for the study of group 11 elements. It discusses one main project divided by ...